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Covalent Bonds
– Forms when 2 atoms share a pair of valence e-
A. Types of Covalent Bonds
1. Single Covalent Bond – two atoms share one pair
of electrons
Ex: F Unshared pair – e- not
2 shared between atoms
●● ●● ●● ●●
●● ●●
● ● ● ● ● ● ● ● ●
● F F● ● F●F● or ● F F●
● ● ●● ●● ●● ●● ●●
What makes this bonding work?
Atoms have 8 e- in their outer level to make them stable
Covalent Bonds (cont.)
Ex: H2
● ● ● or
H H H●H H H
-
Why does H only need 2 e to be stable?
2
first energy level only contains 2 e-
Covalent Bonds (cont.)
2. Double Covalent Bond – 2 pairs of electrons
are shared between atoms
Ex: O2
●● ●● ● ● ● ● ● ●
● ● ● ● ● ● ● or ●
●O O● ● O●● O ●O O●
● ● ● ● ● ● ●
Covalent Bonds (cont.)
3. Triple Covalent Bond – 3 pairs of electrons
are shared between atoms
Ex: N2
●● ●● ●
● ● ● ● ● ● ● ● ● ●
N N ● N ● N● or ●N N●
● ● ● ●
Covalent Lewis Dot Structures
1. Determine the # of valence e- in each atom in the
molecule
(# valence e- = roman numeral for group A atoms)
2. The central atom is often the first atom written & is
usually the atom with the least # of e-. (Exception – H
can’t be the central atom). This is going to be the
atom that needs to share the most electrons.
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