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FLAMEEMISSIONSPECTROSCOPY
Dr AshwiniWadegaonkar
UNIT6: FLAME EMISSIONSPECTROSCOPY
Introduction and theory of atomic emission spectroscopy
Instrumentation of single beam flame emission
spectrophotometer
Measurement ofemission of atomic species
Interferences in emission spectroscopy
Methods of analysis- calibration curve method, Standard
addition method and internal standard method
Qualitative and Quantitative Applications of FES
INTRODUCTION & THEORY
Flame emission spectroscopy is so named because of the
use of a flame to provide the energy of excitation to atoms
introduced into the flame
FES technique deals with the examination of the energy
emitted from a substance when suitably excited.
It is a well known fact that alkali and alkaline earth metals
can be detected by flame test.
All alkali and alkaline earth metal ions give characteristic
colours in a Bunsen flame.
The brightness of the flame colour varies with the amount
of sodium or other metal introduced.
Emission of such particular radiation by sodium
or other metal and the correlation of the emission
intensity with the concentration of the element
form the basis of FES.
ItwasformerlyknownasFlamephotometry
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